​P U B L I C A T I O N S

64) Shan, B.; Fontenot, P.; Greene, A. F.; Wang, B.; Gryspeerdt, S.; Mague, J. T.; Schmehl, R. H.; Donahue, J. P. "Electrocatalytic and Photocatalytic Hydrogen Formation Mediated by Soluble Molybdenum Disulfide Complexes." Manuscript in Preparation.

 

63) Geng, X.; Donahue, J. P.; Mague, J. T.; Pascal, Jr., R. A. "The Hairpin Furans: Easily Prepared Hybrids of Helicenes and Twisted Acenes." Angew. Chem. Int. Ed. 2015, Accepted.

 

62) Pingali. S.; Donahue, J. P.; Payton-Stewart, F. ʺThe Crystal Structure of Tetrahydroberberine, A Pharmacologically Active Naturally Occurring Alkaloid.ʺ Acta Crystallogr., Sect. C 2015, 71, 262-265. DOI: 10.1107/S2053229615004076

 

61) Yan, Y.; Mague, J. T.; Donahue, J. P.; Sproules, S. ʺUnprecendented Spin Localisation in a Metal-Metal Bonded Dirhenium Complex.ʺ Chem. Commun. 2015, 51, 5482-5485. DOI: 10.1039/c4cc09397f

 

60) Chandrasekaran, P.; Greene, A. F.; Lillich, K.; Capone, S.; Mague, J. T.; DeBeer, S.; Donahue, J. P. ″A Structural and Spectroscopic Investigation of Octahedral Platinum Bis(dithiolene) Phosphine Complexes: Phosphine Association Enabled by Platinum-Dithiolene Internal Redox Chemistry.″ Inorg. Chem. 2014, 53, 9192-9205. DOI: 10.1021/ic501273b

 

59) Jayarathne, U.; Chandrasekaran; P. Greene, A. F.; Mague, J. T.; DeBeer, S.; Lancaster, K. M.; Sproules, S.; Donahue, J. P. ″X-ray Absorption Spectroscopy Systematics at the Tungsten L-Edge.″ Inorg. Chem. 2014, 53, 8230-8241. DOI: 10.1021/ic500256a

 

58) Pingali, S.; Donahue, J. P.; Payton-Stewart, F. ″Weak C−H→X (X = O, N) Hydrogen Bonds in the Crystal Structure of Dihydroberberine.″ Acta Crystallogr., Sect. C 2014, 70, 388-391. DOI:10.1107/S2053229614003751

 

57) Cotton, F. A.; Donahue, J. P.; Lin, C.; Murillo, C. A. "Supramolecular Arrays Based on Dimolybdenum Building Blocks." Inorg. Synth. 2014, 36, 82-95. DOI: 10.1002/9781118744994.ch17

 

56) Greene, A. F.; Chandrasekaran, P.; Yan, Y.; Mague, J. T.; Donahue, J. P. ″Element Misidentification in X-ray Crystallography: A Reassessment of the [MCl2(diazadiene)] (M = Cr, Mo, W) Series.″ Inorg. Chem. 2014, 53, 308-317. DOI: 10.1021/ic402246d

 

55) Yue, Y.; Grusenmeyer, T.; Ma, Z.; Zhang, P.; Pham, T. T.; Mague, J. T.; Donahue, J. P.; Schmehl, R. H.; Beratan, D. N.; Rubtsov, I. V. ″Evaluating the Extent of Intramolecular Charge Transfer in the Excited States of Rhenum(I) Donor−Acceptor Complexes with Time-Resolved Vibrational Spectroscopy. ″ J. Phys. Chem. B 2013, 117, 15903-15916. DOI: 10.1021/jp409628e

 

54) Yan, Y.; Keating, C.; Chandrasekaran, P.; Jayarathne, U.; Mague, J. T.; DeBeer, S.; Lancaster, K. M.; Sproules, S.; Rubtsov, I. V.; Donahue, J. P. ″Ancillary Ligand Effects upon Dithiolene Redox Noninnocence in Tungsten Bis(dithiolene) Complexes.″ Inorg. Chem. 2013, 52, 6743-6751. DOI: 10.1021/ic4009174

 

53) Payton-Stewart, F.; Pingali, S. R. K.; Donahue, J. P. ″ The chalcone derivative (E)-1-(4-fluorophenyl)-3-(4-hydroxy-3-methoxyphenyl)prop-2-en-1-one monohydrate.″ Acta Crystallogr., Sect. E. 2013, 69, o558-o559. DOI:10.1107/S160053681300696X

 

52) Jayarathne, U.; Mague, J. T.; Donahue, J. P. ″Hexamethylphosphorus Triamide: A Chloride-for-Dimethylamido, Me2N-, Exchange Reagent.″ Polyhedron 2013, 58, 13-17. DOI:10.1016/j.poly.2012.08.031

 

51) Ferrara, S. J.; Mague, J. T.; Donahue, J. P. ″Synthesis and Structures of Cuprous Triptycylthiolate Complexes.″ Inorg. Chem. 2012, 51, 6567-6576. DOI: 10.1021/ic300124n

 

50) Yan, Y.; Chandrasekaran, P.; Mague, J. T.; DeBeer, S.; Sproules, S.; Donahue, J. P. "Redox-Controlled Interconversion between Trigonal Prismatic and Octahedral Geometries in a Monodithiolene Tetracarbonyl Complex of Tungsten." Inorg. Chem. 2012, 51, 346-361. DOI: 10.1021/ic201748v

 

49) Jayarathne, U.; Williams, K.; Kasyanenko, V.; Mague, J. T.; Rubtsov, I. V.; Donahue, J. P. ″Structural Characterization of [Fe(NO)(mnt)2]1-/2- Salts.″ Polyhedron 2012, 31, 98-103. DOI:10.1016/j.poly.2011.09.001

 

48) Arumugam, K.; Clark, D. S.; Mague, J. T.; Donahue, J. P. ″The Dithiolene Ligand and Tetrathiafulvulvalene Precursor Molecules 4,5-Di(bromomethyl)-1,3-dithiol-2-one and 4,5-Di(methylphosphonic acid)-1,3-dithiol-2-one.″ Acta Crystallogr., Sect. C. 2011, 67, o446-o449. DOI: 10.1107/S0108270111040431

 

47) Sproules, S.; Banerjee, P.; Weyhermüller, T.; Yan, Y.; Donahue, J. P.; Wieghardt, K. ″Monoanionic Molybdenum and Tungsten Tris(dithiolene) Complexes: A Multifrequency Study.″ Inorg. Chem. 2011, 50, 7106-7122. DOI: 10.1021/ic2006265

 

46) Arumugam, K.; Shaw, M. C.; Mague, J. T.; Bill, E.; Sproules, S.; Donahue, J. P. "Long Range Spin Coupling: A Tetraphosphine-Bridged Palladium Dithiolene Dimer." Inorg. Chem. 2011, 50, 2995-3002. DOI: 10.1021/ic102493g

 

45) Ferrara, S. J.; Mague, J. T.; Donahue, J. P. "trans-Bis(N,N-diethylenediamine)-nickel(II) Dibromide." Acta Crystallogr, Sect. E 2011, 67, m48-m49. DOI:10.1107/S1600536810050403

 

44) Jayarathne, U.; Chandrasekaran, P.; Jacobsen, H.; Mague, J. T.; Donahue, J. P. "A Tungsten-Mediated Closed Cycle of Reactivity for the Reduction of CO2 to CO." J. Chem. Soc., Dalton Trans. 2010, 9662-9671. DOI: 10.1039/c0dt00489h

 

43) Kuang, X.-F.; Yu, R.; Wu, X.-Y.; Donahue, J. P.; Huang, J.-S.; Lu, C.-Z. "Assembly of a Metal-Organic Framework by Sextuple Intercatenation of Discrete Adamantane-Like Nanocages." Nature Chemistry 2010, 2, 461-465. DOI:10.1038/nchem.618

 

42) Medina Ramírez, I. E.; Fink, M. J.; Donahue, J. P. "Tetrakis(μ-triisopropylsilanethiolato)-1:2κ4S:S;2:3κ4S:S-bis(triisopropylsilanethiolato)-1κS,3κS-trizinc(II)." Acta Crystallogr, Sect. C. 2009, C65, m475-m477. DOI:10.1107/S0108270109045570

 

41) Yu, R.; Kuang, X.-F.; Wu, X.-Y.; Lu, C.-Z.; Donahue, J. P. "Stabilization and Immobilization of Polyoxometalates in Porous Coordination Polymers through Host-Guest Interactions." Coord. Chem. Rev. 2009, 253, 2872-2890. DOI:10.1016/j.ccr.2009.07.003

 

40) Arumugam, K.; Shaw, M. C.; Chandrasekaran, P.; Villagrán, D.; Gray, T. G.; Mague, J. T.; Donahue, J. P.  "Synthesis, Structures and Properties of 1,2,4,5-Benzenetetrathiolate Linked Group 10 Metal Complexes. Inorg. Chem. 2009, 48, 10591-10607. DOI: 10.1021/ic901257s

 

39) Kasyanenko, V. M.; Lin, Z.; Rubtsov, G. I.; Donahue, J. P.; Rubtsov, I. V. "Energy Transport via Coordination Bonds." J. Chem. Phys. 2009, 131, 154508-1 – 154508-12. DOI: org/10.1063/1.3246862

 

38) Chandrasekaran, P.; Donahue, J. P. "Synthesis of 4,5-Dimethyl-1,3-dithiol-2-one." Org. Synth. 2009, 86, 333-343. DOI: 10.1002/0471264229.os086.32

 

37) Yan, Y.; Mague, J. T.; Donahue, J. P. "A Polymorph of Tetraethylammonium Chloride." Acta Crystallogr, Sect. E 2009, 65, o1491. DOI:10.1107/S160053680902042X

 

36) Chandrasekaran, P.; Arumugam, K.; Jayarathne, U.; Pérez, L.; Mague, J. T.; Donahue, J. P. "Synthesis, Structures and Properties of Mixed Dithiolene-Carbonyl and Dithiolene-Phosphine Complexes of Tungsten." Inorg. Chem. 2009, 48, 2103-2113. DOI: 10.1021/ic802016b

 

35) Jacobsen, H.; Donahue, J. P. "Computational Study of Iron Bis(dithiolene) Complexes: Redox Noninnocent Ligands and Antiferromagnetic Coupling." Inorg. Chem. 2008, 47, 10037-10045. DOI: 10.1021/ic801277r

 

34) Arumugam, K.; Yu, R.; Villgrán, D.; Gray, T. G.; Mague, J. T.; Donahue, J. P. "A Convergent Approach to the Synthesis of Multimetallic Dithiolene Complexes." Inorg. Chem. 2008, 47, 5570-5572. DOI: 10.1021/ic800880s

 

33) Donahue, J. P.; Murillo, C. A. "An Unusual Trigonal D3 Assembly Composed of Molybdate Anions and Multiply Bonded Dimolybdenum Units." Dalton Trans. 2008, 1547-1551. DOI: 10.1039/b714814c

 

32) Yu, R.; Arumugam, K.; Manepalli, A.; Tran, Y.; Schmehl, R.; Jacobsen, H.; Donahue, J. P. "Reversible, Electrochemically Controlled Binding of Phosphine to Iron and Cobalt Bis(dithiolene) Complexes." Inorg. Chem. 2007, 46, 5131-5133. DOI: 10.1021/ic0624569

 

31) Arumugam, K.; Bollinger, J.; Fink, M.; Donahue, J. P. "Preparation and Isolation of Dithiolene Thiophosphoryl Molecules as Stable, Protected Forms of Dithiolene Ligands." Inorg. Chem. 2007, 46, 3283-3288. DOI: 10.1021/ic0700203

 

30) Zhang, Y.; Donahue, J. P.; Li, C.-J. "Gold(III)-Catalyzed Double Hydroamination of o-Alkynylaniline with Terminal Alkynes Leading to N-Vinylindoles." Org. Lett. 2007, 9, 627-630. DOI: 10.1021/ol062918m

 

29) Donahue, J. P.; Jacobsen, H. "Expanding the Scope of the Newman-Kwart Rearrangement. A Computational Assessment." Can. J. Chem. 2006, 84, 1567-1574. DOI: 10.1139/V06-161

 

28) Donahue, J. P. "Thermodynamic Scales for Sulfur Atom Transfer and Oxo-for-Sulfido Exchange Reactions." Chem. Rev. 2006, 106, 4747-4783. DOI: 10.1021/cr050044w.

 

27) Donahue, J. P. "A Closer Look at the Hydroiodination of Propiolic Acid." Synth. Commun. 2006, 36, 3461-3471. DOI: 10.1080/00397910600942826

 

26) Cotton, F. A.; Donahue, J. P.; Gruhn, N. E.; Lichtenberger, D. L.; Murillo, C. A.; Van Dorn, L. O.; Villagrán, D.; Wang, X. "Facilitating Access to the Most Easily Ionized Molecule: A Key Intermediate and Related Compounds." Inorg. Chem. 2006, 45, 201-213. DOI: 10.1021/ic0515709

 

25) Cotton, F. A.; Donahue, J. P.; Huang, P.; Murillo, C. A.; Villagrán, D. Z. "Strong Electronic Coupling between Mo2n+ Units: The Oxidation Products of [Mo2(DAniF)3]2(μ-H)2 and Mo2(DAniF)4." Anorg. Allg. Chem. 2005, 631, 2606-2612. DOI: 10.1002/zaac.200500135

 

24) Cotton, F. A.; Donahue, J. P.; Lichtenberger, D. L.; Murillo, C. A.; Villagrán, D. "Expeditious Access to the Most Easily Ionized Closed-Shell Molecule, W2(hpp)4." J. Am. Chem. Soc. 2005, 125, 10808-10809. DOI: 10.1021/ja0535458

 

23) Medina, I.; Mague, J. T.; Donahue, J. P.; Fink, M. J. "Bis(triphenylsilyl)selenide." Acta Crystallogr., Sect. E. 2005, 61, o2687-o2688. DOI:10.1107/S1600536805023275

 

22) Cotton, F. A.; Donahue, J. P.; Murillo, C. A.; Yu, R. "Synthesis and Structural Characterization of the Molecular Loop [cis-Mo2(N,N'-di-p-anisylformamidinate)2]2(O2C–CH=C=CH–CO2)2." Inorg. Chim. Acta 2005, 358, 1373-1376. DOI:10.1016/j.ica.2004.05.018

 

21) Cotton, F. A.; Donahue, J. P.; Hall, M. B.; Murillo, C. A.; Villagrán, D. "Reaction Products of W(CO)6 with Formamidines; Electronic Structure of a W2(µ-CO)2 Core with Unsymmetric Bridging Carbonyls." Inorg. Chem. 2004, 43, 6954-6964. DOI: 10.1021/ic049116c

 

20) Cotton, F. A.; Donahue, J. P.; Murillo, C. A. "An Asymmetric Edge-Sharing Bioctahedral Complex: (η2-DAniF)MoIII(μ-DAniF)2(μ-O,Cl)MoVCl2 (DAniF = N,N´-di-p-anisylformamidinate)." J. Cluster Sci. 2003, 14, 289-298. DOI: 10.1023/B:JOCL.0000005064.24600.b0

 

19) Cotton, F. A.; Donahue, J. P.; Murillo, C. A.; Pérez, L. M.; Yu, R. "Cyclic Polyamidato Dianions as Bridges between Mo24+ Units: Synthesis, Crystal Structures, Electrochemistry, Absorption Spectra, and Electronic Structures." J. Am. Chem. Soc. 2003, 125, 8900-8910. DOI: 10.1021/ja0358044

 

18) Cotton, F. A.; Donahue, J. P.; Murillo, C. A.; Pérez, L. M. "Polyunsaturated Dicarboxylate Tethers Connecting Dimolybdenum Redox and Chromophoric Centers: Absorption Spectra and Electronic Structures." J. Am. Chem. Soc. 2003, 125, 5486-5492. DOI: 10.1021/ja0343555

 

17) Cotton, F. A.; Donahue, J. P.; Murillo, C. A. "Polyunsaturated Dicarboxylate Tethers Connecting Dimolybdenum Redox and Chromophoric Centers: Synthesis, Structures, and Electrochemistry." J. Am. Chem. Soc. 2003, 125, 5436-5450. DOI: 10.1021/ja029101i

 

16) Cotton, F. A.; Donahue, J. P.; Lin, C.; Murillo, C. A.; Rockwell, J. "A Molecular Pair Having Two Quadruply Bonded Dimolybdenum Units Linked by a Terephthalate Dianion." Acta Crystallogr., Sect. E 2002, 58, m298-m300. DOI: 10.1107/S160053680200884X

 

15) Cotton, F. A.; Daniels, L. M.; Donahue, J. P.; Liu, C. Y.; Murillo, C. A. "The First Designed Syntheses of Bis-Dimetal Molecules in Which the Bridges are Diamidate Ligands." Inorg. Chem. 2002, 41, 1354-1356. DOI: 10.1021/ic025503f

 

14) Cotton, F. A.; Donahue, J. P.; Murillo, C. A. "The First Supramolecular Assemblies Comprised of Dimetal Units and Chiral Dicarboxylates." Inorg. Chem. Commun. 2002, 5, 59-63. DOI: 10.1016/S1387-7003(01)00345-8

 

13) Cotton, F. A.; Donahue, J. P.; Murillo, C. A. "Quadridentate Bridging EO42- (E = S, Mo, W) Ligands and Their Role as Electronic Bridges." Inorg. Chem. 2001, 40, 2229-2233. DOI: 10.1021/ic0012470

 

12) Cotton, F. A.; Donahue, J. P.; Lin, C.; Murillo, C. A. "The Simplest Supramolecular Complexes Containing Pairs of Mo2(formamidinate)3 Units Linked with Various Dicarboxylates: Preparative Methods, Structures, and Electrochemistry." Inorg. Chem. 2001, 40, 1234-1244. DOI: 10.1021/ic000934o

 

11) Clérac, R.; Cotton, F. A.; Donahue, J. P.; Murillo, C. A.; Timmons, D. J. "Completion of the Series of M2(hpp)4Cl2 Compounds from W to Pt: The W, Os, and Pt Compounds." Inorg. Chem. 2000, 39, 2581-2584. DOI: 10.1021/ic991370v

 

10) Lim, B. S.; Donahue, J. P.; Holm, R. H. "Synthesis and Structures of Bis(dithiolene)molybdenum Complexes Related to the Active Sites of the DMSO Reductase Enzyme Family." Inorg. Chem. 2000, 39, 263-273. DOI: 10.1021/ic9908672

 

9) Musgrave, K. B.; Donahue, J. P.; Lorber, C.; Holm, R. H.; Hedman, B.; Hodgson, K. O. "An X-ray Spectroscopic Investigation of Bis(dithiolene)molybdenum(IV,V,VI) and –tungsten(IV,V,

VI) Complexes: Symmetrized Structural Representations of the Active Sites of Molybdoenzymes in the DMSO Reductase Family and of Tungstoenzymes in the AOR and F(M)DH Families." J. Am. Chem. Soc. 1999, 121, 10297-10307. DOI: 10.1021/ja990753p

 

8) Thapper, A.; Donahue, J. P.; Musgrave, K. B.; Willer, M. W.; Nordlander, E.; Hedman, B.; Hodgson, K. O.; Holm, R. H. "The Unperturbed Oxo-Sulfido Functional Group cis-MoVIOS, Related to That in the Xanthine Oxidase Family of Molybdoenzymes: Synthesis, Structural Characterization, and Reactivity Aspects." Inorg. Chem. 1999, 38, 4104-4114. DOI: 10.1021/ic990440v

 

7) Donahue, J. P.; Goldsmith, C. R.; Nadiminti, U.; Holm, R. H. "Synthesis, Structures, and Reactivity of Bis(dithiolene)molybdenum(IV,VI) Complexes Related to the Active Sites of Molybdoenzymes." J. Am. Chem. Soc. 1998, 120, 12869-12881. DOI: 10.1021/ja982914f

 

6) Lorber, C.; Donahue, J. P.; Goddard, C. A.; Nordlander, E.; Holm, R. H. "Synthesis, Structures, and Oxo Transfer Reactivity of Bis(dithiolene)tungsten(IV,VI) Complexes Related to the Active Sites of Tungstoenzymes." J. Am. Chem. Soc. 1998, 120, 8102-8112. DOI: 10.1021/ja981015o

 

5) Donahue, J. P.; Holm, R. H. "3,4-Bis(1-adamantyl)-1,2-dithiete: the First Structurally Characterized Dithiete Unsupported by a Ring or a Benzenoid Frame." Acta Crystallogr., Sect. C 1998, 54, 1175-1178.  DOI: 10.1107/S0108270198002935

 

4) Donahue, J. P.; Lorber, C.; Nordlander, E.; Holm, R. H. "Molybdenum and Tungsten Structural Analogues of the Active Sites of the MoIV + [O] → MoVIO Oxygen Atom Transfer Couple of DMSO Reductases." J. Am. Chem. Soc. 1998, 120, 3259-3260. DOI: 10.1021/ja973917f

 

3) Tucci, G. C.; Donahue, J. P.; Holm, R. H. "Comparative Kinetics of Oxo Transfer to Substrate Mediated by Bis(dithiolene)dioxomolybdenum and –tungsten Complexes." Inorg. Chem. 1998, 37, 1602-1608. DOI: 10.1021/ic971426q

 

2) Tian, Z.-Q.; Donahue, J. P.; Holm, R. H. "Synthesis of New Types of Dithiolene Ligands." Inorg. Chem. 1995, 34, 5567-5572. DOI: 10.1021/ic00126a029

 

1) Holm, R. H.; Donahue, J. P. "A Thermodynamic Scale for Oxygen Atom Transfer Reactions." Polyhedron 1993, 12, 571-589. DOI: 10.1016/S0277-5387(00)84972-4