​P U B L I C A T I O N S

60) ″A Structural and Spectroscopic Investigation of Octahedral Platinum Bis(dithiolene) Phosphine Complexes: Phosphine Association Enabled by Platinum-Dithiolene Internal Redox Chemistry.″ Chandrasekaran, P.; Lillich, K.; Capone, S.; Mague, J. T.; DeBeer, S.; Donahue, J. P. Manuscript in preparation.

 

59) Jayarathne, U.; Chandrasekaran, P.; Greene, A.; Sattler, A.; Mague, J. T.; DeBeer, S.; Parkin, G.; Lancaster, K. M.; Sproules, S.; Donahue, J. P. ″X-ray Absorption Spectroscopy Systematics at the Tungsten L-Edge.″ Submitted.

 

58) ″Weak C−H→X (X = O, N) Hydrogen Bonds in the Crystal Structure of Dihydroberberine.″ Pingali, S. R. K.; Payton-Stewart, F.; Donahue, J. P. Acta Crystallogr., Sect. C 2014, Submitted.

 

57) "Supramolecular Arrays Based on Dimolybdenum Building Blocks." Cotton, F. A.; Donahue, J. P.; Lin, C.; Murillo, C. A. Inorg. Synth. 2014, 36, 82-95.

 

56) ″Element Misidentification in X-ray Crystallography: A Reassessment of the [MCl2(diazadiene)] (M = Cr, Mo, W) Series. ″ Greene, A. F.; Chandrasekaran, P.; Yan, Y.; Mague, J. T.; Donahue, J. P. Inorg. Chem. 2014, 53, 308-317.

 

55) ″Evaluating the Extent of Intramolecular Charge Transfer in the Excited States of Rhenum(I) Donor−Acceptor Complexes with Time-Resolved Vibrational Spectroscopy. ″ Yue, Y.; Grusenmeyer, T.; Ma, Z.; Zhang, P.; Pham, T. T.; Mague, J. T.; Donahue, J. P.; Schmehl, R. H.; Beratan, D. N.; Rubtsov, I. V. J. Phys. Chem. B 2013, 117, 15903-15916.

 

54) ″Ancillary Ligand Effects upon Dithiolene Redox Noninnocence in Tungsten Bis(dithiolene) Complexes.″ Yan, Y.; Keating, C.; Chandrasekaran, P.; Jayarathne, U.; Mague, J. T.; DeBeer, S.; Lancaster, K. M.; Sproules, S.; Rubtsov, I. V.; Donahue, J. P. Inorg. Chem. 2013, 52, 6743-6751.

 

53) ″Structure of the Chalcone Derivative (E)-3-(3-Methoxy-4-hydroxyphenyl)-1-(4-fluorophenyl)-prop-2-ene-1-one Monohydrate. ″ Payton-Stewart, F.; Pingali, S. R. K.; Donahue, J. P. Acta Crystallogr., Sect. E. 2013, 69, o558-o559.

 

52) ″Hexamethylphosphorus Triamide: A Chloride-for-Dimethylamido, Me2N-, Exchange Reagent.″ Jayarathne, U.; Mague, J. T.; Donahue, J. P. Polyhedron 2013, 58, 13-17.

 

51) ″Synthesis and Structures of Cuprous Triptycylthiolate Complexes.″ Ferrara, S. J.; Mague, J. T.;Donahue, James P. Inorg. Chem. 2012, 51, 6567-6576.



50) "Trigonal Prismatic vs. Octahedral Coordination Geometry in Monodithiolene Tetracarbonyl Complexes of Tungsten." Yan, Y.; Chandrasekaran, P.; Mague, J. T.; DeBeer, S.; Sproules, S.;Donahue, James P. Inorg. Chem. 2012, 51, 346-361.



49) ″Structural Characterization of [Fe(NO)(mnt)2]1-/2- Salts.″ Jayarathne, U.; Williams, K.; Kasyanenko, V.; Mague, J. T.; Rubtsov, I. V.;Donahue, James P. Polyhedron 2012, 31, 98-103.



48) ″The Dithiolene Ligand and Tetrathiafulvulvalene Precursor Molecules 4,5-Di(bromomethyl)-1,3-dithiol-2-one and 4,5-Di(methylphosphonic acid)-1,3-dithiol-2-one.″ Arumugam, K.; Clark, D. S.; Mague, J. T.;Donahue, James P. Acta Crystallogr., Sect. C. 2011, 67, o446-o449.



47) ″Monoanionic Molybdenum and Tungsten Tris(dithiolene) Complexes: A Multifrequency Study.″ Sproules, S.; Banerjee, P.; Weyhermüller, T.; Yan, Y.;Donahue, James P.; Wieghardt, K. Inorg. Chem. 2011, 50, 7106-7122.



46) "Long Range Spin Coupling: A Tetraphosphine-Bridged Palladium Dithiolene Dimer." Arumugam, K.; Shaw, M. C.; Mague, J. T.; Bill, E.; Sproules, S.; Donahue, James P. Inorg. Chem. 2011, 50, 2995-3002.



45) "trans-Bis(N,N-diethylenediamine)-nickel(II) Dibromide." Ferrara, S. J.; Mague, J. T.;Donahue, James P. Acta Crystallogr, Sect. E 2011, 67, m48-m49.



44) "A Tungsten-Mediated Closed Cycle of Reactivity for the Reduction of CO2 to CO." Jayarathne, U.; Chandrasekaran, P.; Jacobsen, H.; Mague, J. T.;Donahue, James P. J. Chem. Soc., Dalton Trans. 2010, 9662-9671.



43) "Assembly of a Metal-Organic Framework by Sextuple Intercatenation of Discrete Adamantane-Like Nanocages." Kuang, X.-F.; Yu, R.; Wu, X.-Y.;Donahue, James P.; Huang, J.-S.; Lu, C.-Z. Nature Chemistry 2010, 2, 461-465.



42) "Structure of [(iPr3SiS)Zn(µ-SSiiPr3)2Zn(µ-SSiiPr3)2Zn(SSiiPr3)]." Medina Ramírez, I. E.; Fink, M. J.;Donahue, James P. Acta Crystallogr, Sect. C. 2009, C65, m475-m477.



41) "Stabilization and Immobilization of Polyoxometalates in Porous Coordination Polymers through Host-Guest Interactions." Yu, R.; Kuang, X.-F.; Wu, X.-Y.; Lu, C.-Z.;Donahue, James P. Coord. Chem. Rev. 2009, 253, 2872-2890.



40) "Synthesis, Structures and Properties of 1,2,4,5-Benzenetetrathiolate Linked Group 10 Metal Complexes." Arumugam, K.; Shaw, M. C.; Chandrasekaran, P.; Villagrán, D.; Gray, T. G.; Mague, J. T.;Donahue, James P. Inorg. Chem. 2009, 48, 10591-10607.



39) "Energy Transport via Coordination Bonds." Kasyanenko, V. M.; Lin, Z.; Rubtsov, G. I.;Donahue, James P.; Rubtsov, I. V. J. Chem. Phys. 2009, 131, 154508-1 – 154508-12.



38) "Synthesis of 4,5-Dimethyl-1,3-dithiol-2-one." Chandrasekaran, P.;Donahue, James P. Org. Synth. 2009, 86, 333-343.



37) "A Polymorph of Tetraethylammonium Chloride." Yan, Y.; Mague, J. T.;Donahue, James P. Acta Crystallogr, Sect. E 2009, 65, o1491.



36) "Synthesis, Structures and Properties of Mixed Dithiolene-Carbonyl and Dithiolene-Phosphine Complexes of Tungsten." Chandrasekaran, P.; Arumugam, K.; Jayarathne, U.; Pérez, L.; Mague, J. T.;Donahue, James P. Inorg. Chem. 2009, 48, 2103-2113.



35) "Computational Study of Iron Bis(dithiolene) Complexes: Redox Noninnocent Ligands and Antiferromagnetic Coupling." Jacobsen, H.;Donahue, James P. Inorg. Chem. 2008, 47, 10037-10045.



34) "A Convergent Approach to the Synthesis of Multimetallic Dithiolene Complexes." Arumugam, K.; Yu, R.; Villgrán, D.; Gray, T. G.; Mague, J. T.;Donahue, James P. Inorg. Chem. 2008, 47, 5570-5572.



33) "An Unusual Trigonal D3 Assembly Composed of Molybdate Anions and Multiply Bonded Dimolybdenum Units."Donahue, James P.; Murillo, C. A. Dalton Trans. 2008, 1547-1551.



32) "Reversible, Electrochemically Controlled Binding of Phosphine to Iron and Cobalt Bis(dithiolene) Complexes." Yu, R.; Arumugam, K.; Manepalli, A.; Tran, Y.; Schmehl, R.; Jacobsen, H.;Donahue, James P. Inorg. Chem. 2007, 46, 5131-5133.



31) "Preparation and Isolation of Dithiolene Thiophosphoryl Molecules as Stable, Protected Forms of Dithiolene Ligands." Arumugam, K.; Bollinger, J.; Fink, M.;Donahue, James P. Inorg. Chem. 2007, 46, 3283-3288.



30) "Gold(III)-Catalyzed Double Hydroamination of o-Alkynylaniline with Terminal Alkynes Leading to N-Vinylindoles." Zhang, Y.;Donahue, James P.; Li, C. J. Org. Lett. 2007, 9, 627-630.



29) "Expanding the Scope of the Newman-Kwart Rearrangement. A Computational Assessment."Donahue, James P.; Jacobsen, H. Can. J. Chem. 2006, 84, 1567-1574.



28) "Thermodynamic Scales for Sulfur Atom Transfer and Oxo-for-Sulfido Exchange Reactions."Donahue, James P. Chem. Rev. 2006, 106, 4747-4783.



27) "A Closer Look at the Hydroiodination of Propiolic Acid."Donahue, James P. Synth. Commun. 2006, 36, 3461-3471.



26) "Facilitating Access to the Most Easily Ionized Molecule: A Key Intermediate and Related Compounds." Cotton, F. A.; Donahue, James P.; Gruhn, N. E.; Lichtenberger, D. L.; Murillo, C. A.; Van Dorn, L. O.; Villagrán, D.; Wang, X. Inorg. Chem. 2006, 45, 201-213.



25) "Strong Electronic Coupling between Mo2n+ Units: The Oxidation Products of [Mo2(DAniF)3]2(μ-H)2 and Mo2(DAniF)4." Cotton, F. A.;Donahue, James P.; Huang, P.; Murillo, C. A.; Villagrán, D. Z. Anorg. Allg. Chem. 2005, 631, 2606-2612.



24) "Expeditious Access to the Most Easily Ionized Closed-Shell Molecule, W2(hpp)4." Cotton, F. A.;Donahue, James P.; Lichtenberger, D. L.; Murillo, C. A.; Villagrán, D. J. Am. Chem. Soc. 2005, 125, 10808-10809.



23) "Bis(triphenylsilyl)selenide." Medina, I.; Mague, J. T.;Donahue, James P.; Fink, M. J. Acta Crystallogr., Sect. E. 2005, 61, o2687-o2688.

22) "Synthesis and Structural Characterization of the Molecular Loop [cis-Mo2(N,N'-di-p-anisylformamidinate)2]2(O2C–CH=C=CH–CO2)2." Cotton, F. A.;Donahue, James P.; Murillo, C. A.; Yu, R. Inorg. Chim. Acta 2005, 358, 1373-1376.



21) "Reaction Products of W(CO)6 with Formamidines; Electronic Structure of a W2(µ-CO)2 Core with Unsymmetric Bridging Carbonyls." Cotton, F. A.;Donahue, James P.; Hall, M. B.; Murillo, C. A.; Villagrán, D. Inorg. Chem. 2004, 43, 6954-6964.



20) "An Asymmetric Edge-Sharing Bioctahedral Complex: (η2-DAniF)MoIII(μ-DAniF)2(μ-O,Cl)MoVCl2 (DAniF = N,N´-di-p-anisylformamidinate)." Cotton, F. A.;Donahue, James P.; Murillo, C. A. J. Cluster Sci. 2003, 14, 289-298.



19) "Cyclic Polyamidato Dianions as Bridges between Mo24+ Units: Synthesis, Crystal Structures, Electrochemistry, Absorption Spectra, and Electronic Structures." Cotton, F. A.;Donahue, James P.; Murillo, C. A.; Pérez, L. M.; Yu, R. J. Am. Chem. Soc. 2003, 125, 8900-8910.



18) "Polyunsaturated Dicarboxylate Tethers Connecting Dimolybdenum Redox and Chromophoric Centers: Absorption Spectra and Electronic Structures." Cotton, F. A.;Donahue, James P.; Murillo, C. A.; Pérez, L. M. J. Am. Chem. Soc. 2003, 125, 5486-5492.



17) "Polyunsaturated Dicarboxylate Tethers Connecting Dimolybdenum Redox and Chromophoric Centers: Synthesis, Structures, and Electrochemistry." Cotton, F. A.;Donahue, James P.; Murillo, C. A. J. Am. Chem. Soc. 2003, 125, 5436-5450.



16) "A Molecular Pair Having Two Quadruply Bonded Dimolybdenum Units Linked by a Terephthalate Dianion." Cotton, F. A.;Donahue, James P.; Lin, C.; Murillo, C. A.; Rockwell, J. Acta Crystallogr., Sect. E 2002, 58, m298-m300.



15) "The First Designed Syntheses of Bis-Dimetal Molecules in Which the Bridges are Diamidate Ligands." Cotton, F. A.; Daniels, L. M.;Donahue, James P.; Liu, C. Y.; Murillo, C. A. Inorg. Chem. 2002, 41, 1354-1356.



14) "The First Supramolecular Assemblies Comprised of Dimetal Units and Chiral Dicarboxylates." Cotton, F. A.;Donahue, James P.; Murillo, C. A. Inorg. Chem. Commun. 2002, 5, 59-63.



13) "Quadridentate Bridging EO42- (E = S, Mo, W) Ligands and Their Role as Electronic Bridges." Cotton, F. A.;Donahue, James P.; Murillo, C. A. Inorg. Chem. 2001, 40, 2229-2233.



12) "The Simplest Supramolecular Complexes Containing Pairs of Mo2(formamidinate)3 Units Linked with Various Dicarboxylates: Preparative Methods, Structures, and Electrochemistry." Cotton, F. A.;Donahue, James P.; Lin, C.; Murillo, C. A. Inorg. Chem. 2001, 40, 1234-1244.



11) "Completion of the Series of M2(hpp)4Cl2 Compounds from W to Pt: The W, Os, and  Pt  Compounds." Clérac, R.; Cotton, F. A.;Donahue, James P.; Murillo, C. A.; Timmons, D. J. Inorg. Chem. 2000, 39, 2581-2584.



10) "Synthesis and Structures of Bis(dithiolene)molybdenum Complexes Related to the Active Sites of the DMSO Reductase Enzyme Family." Lim, B. S.;Donahue, James P.; Holm, R. H. Inorg. Chem. 2000, 39, 263-273.



9) "An   X-ray    Spectroscopic    Investigation    of    Bis(dithiolene)molybdenum(IV,V,VI)   and tungsten(IV,V,VI) Complexes: Symmetrized Structural Representations of the Active Sites of Molybdoenzymes in the DMSO Reductase Family and of Tungstoenzymes in the AOR and F(M)DH Families." Musgrave, K. B.;Donahue, James P.; Lorber, C.; Holm, R. H.; Hedman, B.; Hodgson, K. O. J. Am. Chem. Soc. 1999, 121, 10297-10307.



8) "The Unperturbed Oxo-Sulfido Functional Group cis-MoVIOS, Related to That in the Xanthine Oxidase Family of Molybdoenzymes: Synthesis, Structural Characterization, and Reactivity Aspects." Thapper, A.;Donahue, James P.; Musgrave, K. B.; Willer, M. W.; Nordlander, E.; Hedman, B.; Hodgson, K. O.; Holm, R. H. Inorg. Chem. 1999, 38, 4104-4114.



7) "Synthesis, Structures, and Reactivity of Bis(dithiolene)molybdenum(IV,VI) Complexes Related to the Active Sites of Molybdoenzymes."Donahue, James P.; Goldsmith, C. R.; Nadiminti, U.; Holm, R. H. J. Am. Chem. Soc. 1998, 120, 12869-12881.



6) "Synthesis, Structures, and Oxo Transfer Reactivity of Bis(dithiolene)tungsten(IV,VI) Complexes Related to the Active Sites of Tungstoenzymes." Lorber, C.;Donahue, James P.; Goddard, C. A.; Nordlander, E.; Holm, R. H. J. Am. Chem. Soc. 1998, 120, 8102-8112.



5) "3,4-Bis(1-adamantyl)-1,2-dithiete: the First Structurally Characterized Dithiete Unsupported by a Ring or a Benzenoid Frame."Donahue, James P.; Holm, R. H. Acta Crystallogr., Sect. C 1998, 54, 1175-1178.



4) "Molybdenum and Tungsten Structural Analogues of the Active Sites of the MoIV + [O]  MoVIO Oxygen Atom Transfer Couple of DMSO Reductases."Donahue, James P.; Lorber, C.; Nordlander, E.; Holm, R. H. J. Am. Chem. Soc. 1998, 120, 3259-3260.



3) "Comparative Kinetics of Oxo Transfer to Substrate Mediated by Bis(dithiolene)dioxomolybdenum and –tungsten Complexes." Tucci, G. C.;Donahue, James P.; Holm, R. H. Inorg. Chem. 1998, 37, 1602-1608.



2) "Synthesis of New Types of Dithiolene Ligands." Tian, Z.-Q.;Donahue, James P.; Holm, R. H. Inorg. Chem. 1995, 34, 5567-5572.

1) "A Thermodynamic Scale for Oxygen Atom Transfer Reactions." Holm, R. H.;Donahue, James P. Polyhedron 1993, 12, 571-589.